Deuteron UV 1240

Cationic UV photoinitiator for epoxy and vinyl ether resins. Cures oxirane and oxetane systems under a mercury lamp with low shrinkage, no benzene emission and only slight odour.

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Deuteron UV 1240 is a solution of bis(dodecylphenyl)iodonium hexafluoroantimonate in a reactive solvent. It is a photoinitiator for cationic polymerisation, which is a different cure mechanism from the free-radical acrylate systems that dominate UV coating.

It suits resins based on oxirane or oxetane groups, meaning epoxy resins and vinyl ethers. Adding it lets a formulator use UV light to drive the polymerisation of those systems.

Polymerisation is initiated by UV between 220 and 250 nm, with maximum absorption at 240 nm. Suitable light sources are high-pressure mercury lamps with strong emission in that band.

It contains no volatile solvents, so it does not add to film shrinkage. The carrier here is propylene carbonate; the companion grade UV 1242 uses a C12/C14 glycidyl ether instead.

Typical properties

PropertyTypical value
AppearanceReddish viscous liquid
Active content50 percent
Reactive thinnerPropylene carbonate
Densityapprox. 1.24 g/cm³
Absorption range220 to 250 nm, maximum at 240 nm
Cure mechanismCationic

Dosage: A typical addition range of 1.0 to 5.0 percent. The level depends on the system and the curing speed wanted, so determine it with a ladder study.

Typical values from the manufacturer's technical data sheet. They describe the product, they are not a specification. We will send the current TDS and the batch documentation your qualification needs.

Need this in your system?

Tell us the binder system, the property you are targeting, and the volume you expect. We will confirm the grade, send the documentation, and ship a sample from North American stock.

Applications

Overprint varnishes

Cationic cure with low shrinkage over the print.

UV silk-screen inks

Thick deposits where shrinkage would otherwise show.

UV flexographic inks

Cationic systems on film and paper.

UV lamination adhesives

Cure through where free-radical systems are oxygen inhibited.

Metal coatings

Adhesion on a substrate that resists it.

Plastics coatings

Adhesion on difficult plastic substrates.

It is specified where the formulation needs low shrinkage, no benzene emission, only slight odour, flexibility in the cured film, and adhesion on difficult substrates.

Handling and dispersion

Deuteron UV cationic initiators can be incorporated into the binder with a high-speed stirrer or another aggregate such as a dissolver.

Several routes exist to push performance further: co-catalysts such as ITX, catalysis by copper naphthenates, raising the curing temperature, and adding multifunctional alcohols such as TMP. Ask us for the UV initiator brochure before designing the trial.

Packaging, storage, and regulatory status

Package sizes: Plastic canister.

Storage: 12 months at room temperature in dry conditions, in the original tightly closed containers. Do not expose to direct sunlight.

Under Regulation (EC) No. 1272/2008 Deuteron UV 1240 is classified as a dangerous product and must be labelled. Read the safety data sheet before handling.

Frequently asked questions

How is cationic UV cure different from the usual acrylate systems?

Free-radical acrylate cure is fast but shrinks, is inhibited by oxygen at the surface, and stops the moment the lamp goes off. Cationic cure runs on an acid generated by the photoinitiator, so it continues in the dark after exposure, is not oxygen inhibited, and shrinks less. That is why it is chosen for adhesion on difficult substrates and for thick deposits.

What lamp do I need?

One with strong emission between 220 and 250 nm, since maximum absorption is at 240 nm. High-pressure mercury lamps are the suitable source. An LED source emitting at 385 or 395 nm will not initiate this photoinitiator.

What resins does it work with?

Resins based on oxirane or oxetane groups, which means epoxy resins and vinyl ethers. It is soluble in those binder systems including the standard solvents and reactive diluents.

Can I speed the cure up?

Yes, several ways: a co-catalyst such as ITX, catalysis by copper naphthenates, a higher curing temperature, or adding a multifunctional alcohol such as TMP. Ask us for the UV initiator brochure, which covers each option.

Why is the shelf life only 12 months?

It is a photoinitiator, so light and time are both working against it. Keep it in the original tightly closed container, out of direct sunlight, at room temperature. Most of the Deuteron range carries 24 months; this one does not.

Can I get the TDS and SDS for Deuteron UV 1240?

Yes. We send the Technical Data Sheet (TDS), Safety Data Sheet (SDS), Regulatory Information Sheet, and UV initiator brochure on request, in the manufacturer's current revision. Use Request TDS or SDS above and tell us what your qualification review needs.

Related products

Deuteron MM 110

Matting dispersion for the UV curable systems this initiator cures.

Deuteron MM 100

The same matting dispersion without a wetting agent.

Deuteron Wax PP/2

Wax additive usable in 100 percent and UV curable systems.

Evaluating Deuteron UV 1240?

Tell us the system you are formulating and the property you need to hit. We will confirm the grade, send the data sheet, and ship a sample.